Add documentation for -starttls (s_client) and -id_prefix (s_server).

PR: 542

doc/apps/s_client.pod

@@ -33,6 +33,7 @@ B<openssl> B<s_client>
 [B<-no_tls1>]
 [B<-bugs>]
 [B<-cipher cipherlist>]
+[B<-starttls protocol>]
 [B<-engine id>]
 [B<-rand file(s)>]
 
@@ -163,6 +164,12 @@ the server determines which cipher suite is used it should take the first
 supported cipher in the list sent by the client. See the B<ciphers>
 command for more information.
 
+=item B<-starttls protocol>
+
+send the protocol-specific message(s) to switch to TLS for communication.
+B<protocol> is a keyword for the intended protocol.  Currently, the only
+supported keyword is "smtp".
+
 =item B<-engine id>
 
 specifying an engine (by it's unique B<id> string) will cause B<s_client>

doc/apps/s_server.pod

@@ -42,6 +42,7 @@ B<openssl> B<s_server>
 [B<-WWW>]
 [B<-HTTP>]
 [B<-engine id>]
+[B<-id_prefix arg>]
 [B<-rand file(s)>]
 
 =head1 DESCRIPTION
@@ -209,6 +210,13 @@ to attempt to obtain a functional reference to the specified engine,
 thus initialising it if needed. The engine will then be set as the default
 for all available algorithms.
 
+=item B<-id_prefix arg>
+
+generate SSL/TLS session IDs prefixed by B<arg>. This is mostly useful
+for testing any SSL/TLS code (eg. proxies) that wish to deal with multiple
+servers, when each of which might be generating a unique range of session
+IDs (eg. with a certain prefix).
+
 =item B<-rand file(s)>
 
 a file or files containing random data used to seed the random number